This follows from the fact that all circles are similar. It’s quite fun to figure out why using the definition of a circle and the definition of a similarity transformation. (I can supply the answer later if you want.)
Now, a similarity transformation with scale factor transforms any length by a scale factor of , including the arc length. So, just as the radius gets multiplied by , so does the arc length. This means that the ratio between the arc length and the radius stays equivalent no matter what the radius; in other words, the arc length is proportional to the radius.
So this tell us that
Setting the radius equal to 1 tells us what the constant is: it’s just the arc length for a circle of radius 1, which is exactly the radian measure of the angle.